Difference between duplex SS and 304 SS

Aug 13, 2025 Leave a message

Duplex stainless steeland 304 stainless steel are two types of stainless steel with very different properties and applications. The main differences are reflected in chemical composition, microstructure, mechanical properties, corrosion resistance, cost, and application areas. The following is a detailed comparison:

 

 

Chemical Composition

 

From a chemical composition perspective, the core characteristic of 304 stainless steel is that it relies on nickel to maintain its austenitic structure, with no molybdenum (Mo) added. The core characteristics of duplex stainless steel (such as 2205) are high chromium, added molybdenum, and nitrogen, with a lower nickel content. The following is a composition table of 2205 duplex stainless steel and 304 stainless steel:

Element Chromium (Cr) Nickel (Ni) Molybdenum (Mo) Nitrogen (N) Carbon (C) Iron (Fe)
2205 21–23% 4.5–6.5% 2.5–3.5% 0.14–0.20% ≤0.03% Balance
304 18–20% 8–10.5% ≤0.75% ≤0.10% ≤0.08% Balance

 

 

Microstructure

 

  • Duplex stainless steel: ~50% ferrite + ~50% austenite. This duplex structure provides high strength and excellent resistance to chloride stress corrosion cracking.
  • 304 stainless steel: This austenitic stainless steel consists primarily of a single austenite phase (no ferrite at room temperature). It has excellent ductility, formability, and weldability, but is more susceptible to stress corrosion cracking in chloride environments. 

 

 

Mechanical Properties

 

In terms of mechanical properties, the yield strength of duplex steel is more than twice that of 304, and its load-bearing capacity is stronger; 304 has a higher elongation, which means better formability.

Property Yield Strength (MPa) Tensile Strength (MPa) Elongation (%) Hardness (HB)
2205 ~450–550 ~650–800 25–30 ~250
304 ~200–250 ~500–600 40–60 ~150–160

 

 

Corrosion Resistance

Duplex stainless steel

Duplex stainless steel

Offers superior corrosion resistance in harsh environments. Its molybdenum and nitrogen content provides high resistance to chloride pitting and crevice corrosion, and its resistance to stress corrosion cracking (SCC) far exceeds that of 304. It performs exceptionally well in chemical and marine environments.

 

 

304 stainless steel

Offers excellent corrosion resistance in the atmosphere, freshwater, and mildly corrosive environments (such as food contact), but is susceptible to pitting corrosion in high-salt environments.

304 stainless steel

 

Cost

 

  • Duplex stainless steel: Its high alloy content (Mo and N) results in a higher per-kilogram raw material cost. However, its higher strength allows for reduced material thickness, thereby reducing overall project costs in structural applications.
  • 304 stainless steel: Due to its high nickel content (8%-10.5%) and the high price volatility of nickel (approximately $20,000 per ton), its cost is significantly affected by nickel prices, resulting in high and unstable prices.

 

 

Application

 

Duplex Stainless Steel 304 Stainless Steel
Offshore oil & gas platforms Kitchen equipment, food processing machinery
Marine environments Building facades, railings, and decorative parts
Chemical processing equipment Chemical containers for mild environments
Pulp & paper digesters Heat exchangers (non-chloride conditions)
Storage tanks for aggressive media Domestic water piping

 

Conclusion

 

If you require higher strength, improved chloride corrosion resistance, and SCC resistance, duplex stainless steel is a better choice (especially in marine or chemical environments). If you require ease of fabrication, good high-temperature performance, and lower cost, 304 is often the preferred choice. As a steel pipe manufacturer with over 20 years of experience, TORICH ensures you receive a quality product.

 

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